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2. To prevent insect proliferation, the air inside a greenhouse must be kept at a constant concentration of a volatile pesticide (A) equal to 0.5
2. To prevent insect proliferation, the air inside a greenhouse must be kept at a constant concentration of a volatile pesticide (A) equal to 0.5 mM. Once the pesticide is in the air, it decomposes at a constant rate of 0.5 mmol/h. The pesticide is available as an aqueous solution at a concentration of 1 M. To make up for the decomposition of pesticide in the air, the liquid solution will be encapsulated in cylindrical fibers of a polymer (B) with an outside diameter of 0.3 mm, a wall thickness of 0.03 mm, and a length of 10 cm. Assume that (i) the greenhouse air is perfectly mixed, and (ii) there is no flow of air in or out of the greenhouse at any time. Also assume pseudo- steady diffusion of the pesticide through the fiber wall, and that the concentration of pesticide inside the fibers remains at 1 M. Neglect diffusion through the ends of the cylindrical fibers. Estimate the number of fibers loaded with the pesticide solution that will need to be exposed to the air in the greenhouse to make up for the decomposition of pesticide in the air. Additional information: 2 Diffusivity of pesticide in polymer: DAB = 107 cm/s Equilibrium relation liquid/polymer: CA.polymer = 0.005 CA,water Equilibrium relation polymer/air: CA polymer =0.1 CA,air
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