1. 20.0 mL water sample was titrated with 0.0100 M EDTA solution that required 14.50 mL for CaCO3 hardness. The total hardness of the water sample in terms of CaCO3 (MW = 100.1 g/mole) in parts per million is _________?

Note: Express final answer using least number of significant figures.

2. If 35.2 mL of EDTA solution is required to reach the endpoint with 0.3120-g of primary standard grade CaCO3 (MW = 100.1 g/mole), the normal concentration of the EDTA (MW = 292.24) solution is _________ N?