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2ClO 2 (aq) + 2OH - (aq) ---> ClO 3 - (aq) + ClO 2 - (aq) + H 2 O (l) The above reaction

2ClO2(aq) + 2OH-(aq) ---> ClO3-(aq) + ClO2-(aq) + H2O(l)

The above reaction was studied (at a particular temperature) and the following data (for rate = -d[ClO2]/dt) were obtained:

[ClO2]0 [OH-]0 Initial Rate
(mol/L) (mol/L) (mol L-1 s-1)
0.460 0.210 1.26101
0.460 0.105 6.31
0.230 0.210 3.15

Which of the following expressions for the rate law are consistent with the above experimental data.

Note that the rate constant may be different for each of the choices below (i.e. k in choice A may be not equal to k in choice B etc).

(state whether its yes or no for each) Yes or No k[OH-][ClO2] = d[ClO3-]/dt Yes or No d[ClO3-]/dt = k[ClO2]2[OH-]2 Yes or No k[OH-][ClO2]2 = -d[ClO2]/dt Yes or No k[OH-][ClO2]2 = d[ClO2-]/dt Yes or No k[ClO2]2[OH-] = -d[OH-]/dt

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