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( 3 5 points ) A catalytic converter is used to catalyze the following chemical reaction: C O + 1 2 O 2 C O

(35 points) A catalytic converter is used to catalyze the following chemical reaction:
CO+12O2CO2
The concentration of CO(species A) is reduced by passing the exhaust gases over the catalyst surface, and the rate of reduction for CO species consumption at the catalyst is governed by a first-order reaction with rate constant k1''=0.050ms. As a first approximation, assume that CO reaches the surface by one-dimensional diffusion through a thin gas film above the catalyst surface. The gas film thickness is L=1.0mm. The diffusion coefficient of CO in the gas is 8.7510-5m2s. The exhaust gas is at 400C and 1.1 bars and the mole fraction at x=L is
xCO,L=0.0045. As a first approximation, assume the film is stagnant (the medium is stationary)
and an ideal gas. Evaluate the system at steady state.
(a) What is the CO concentration in the gas film at height L, meaning CA(x=L) in molm3?
(b) Start from the general mass diffusion equation and determine the simplified mass diffusion
equation for this system. Solve for the general solution of the concentration profile CA(x).
(c) What are the boundary conditions to solve CA(x) in (a) written in terms of CA?
(d) Solve for the CO concentration profile CA(x) in the gas film above the catalyst.
(e) What is the molar concentration of CO in the gas at the catalyst surface?
(f) Catalytic converters have very high catalyst surface area using honeycomb structures. What
would be the molar rate of CO removal for a catalyst surface area A=12,000m2?
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