Answered step by step
Verified Expert Solution
Question
1 Approved Answer
3. Partial oxidation of cholesterol to cholest-4en-3one is an important step in steroid synthesis for some oral contraceptives. The reaction can be catalyzed enzymatically, using
3. Partial oxidation of cholesterol to cholest-4en-3one is an important step in steroid synthesis for some oral contraceptives. The reaction can be catalyzed enzymatically, using oxygen as an oxidizer. (A) cholesterol (B) cholestenone The overall reaction is cholesterol+O2cholestenone+H2O2. The rate expression is: rcholesterol=k2+CcholesterolCO2k1CcholesterolCO2k1=0.001LmolL1s1andk2=5106(M)2 In the aqueous solvent required for the enzyme to function, the solubility of oxygen is 1mM. A batch membrane reactor is used to perform the reaction. The membrane is permeable to oxygen. Oxygen from the outside air crosses the membrane and enters the reactor at a rate =kmembC02. The rate constant kmemb=0.01s1. The batch reactor initially contains 15mM cholesterol, and is saturated with O2. Plot concentrations of cholesterol, cholestenone, O2 and H2O2 vs. time. How long will it take to convert 80 percent of the cholesterol to cholestenone
Step by Step Solution
There are 3 Steps involved in it
Step: 1
Get Instant Access to Expert-Tailored Solutions
See step-by-step solutions with expert insights and AI powered tools for academic success
Step: 2
Step: 3
Ace Your Homework with AI
Get the answers you need in no time with our AI-driven, step-by-step assistance
Get Started