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5. In the previous problem, we saw that 'H NMR data includes chemical shift, multiplicity, and integration for each peak. There's one more piece of
5. In the previous problem, we saw that 'H NMR data includes chemical shift, multiplicity, and integration for each peak. There's one more piece of information: the coupling constant (J-value). There is no coupling constant for a singlet peak (because there is no coupling!). All other peaks will have a coupling constant. This is reported in Hertz (Hz), and it is found by measuring the distances between the lines of the peak. Typical J-values are found in the bottom right corner of the chemical shift chart (posted on Brightspace). The most common J-value is 7 Hz. This is the value observed between neighboring protons when all of the bonds are freely-rotating. When there is restricted rotation (due to pi bonds or rings), the J-value can be larger or smaller than 7 Hz. Consider the following 'H NMR spectrum. The integral values are shown near the peaks. 2H elle 0 2 3 PPM The data from this spectrum is written out like this: 2.45 (q, J = 7 Hz, 2 H); 2.12 (s, 3H); 1.06 (t, J = 7 Hz, 3 H) Notice that the distances between the lines in the quartet and the triplet appear to be the same, because they are the same. Both peaks have a coupling constant of 7 Hz. Based on the integrations, this molecule probably has one methylene group (2 H) and two different methyl groups (3 H each). Draw a reasonable structure that is consistent with this spectrum. The formula is C4H20
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