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6 . 1 0 . The critical step in Motorola's proposed process for producing ultra pure solar - cell grade silicon is the reaction S

6.10. The critical step in Motorola's proposed process for producing ultra pure
solar-cell grade silicon is the reaction
Si([ commercial grade, ],[ solid, 98% pure ])+SiF4([ gas, ],[ pure ])2SiF2([ gas, ],[ pure ])dots exothermic
The SiF2 is then decomposed elsewhere to produce pure silicon. Thermody-
namics says that at the chosen operating temperature of 1,350K, the reaction
should only become appreciable when the pressure falls below 100Pa. The
reactor will be a vertical 0.4-m-i.d. tube packed with 6-mm silicon particles
(=0.5). Reactant gas (pure SiF4) will enter the reactor at 2,000Pa and 1,350K,
and 1.2m downstream we expect the pressure to have dropped to 100Pa. From
here on reaction takes off and conversion to product is soon complete. Estimate
the production rate of silicon (kgh) obtainable from this reactor.
Data:
SiF4=410-5kgms(estimated)
(mw)Si=0.028
(mw)SiF4=0.104
(CpCv)SiF4=1.15(estimated)
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