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6 . How could their mass spectra be used to distinguish between the following compounds? Can you show the Maclafferty rearrangement with 2 - Pentaone?

6. How could their mass spectra be used to distinguish between the following compounds?
Can you show the Maclafferty rearrangement with 2-Pentaone?
Can you show how 3-Methyl-2- Butanone does not have any gamma hydrogens ?
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