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A 3 1 gram sample of copper ( csp ( Cu ) = 0 . 3 8 5 J / ( g K ) )

A 31 gram sample of copper (csp(Cu)=0.385 J/(g K)) is placed in a constant-pressure calorimeter containing 100 g of liquid water at 99.5\deg C, right below the boiling temperature of 99.6\deg C. After some time the temperature of the water becomes constant at 92.3\deg C. What was the initial temperature of the copper block? Assume no heat is lost to the surroundings.

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