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(a) Aproximate the minimun concentration of Fe+3 oxidizer needed to passivate any of the type 430 stainless steels of the Figure below in 1N sulfuric
(a) Aproximate the minimun concentration of Fe+3 oxidizer needed to passivate any of the type 430 stainless steels of the Figure below in 1N sulfuric acid, assuming that the acid is contaminated to a level of 103mol/L with corrosion product Fe+2. Assume that the exchange current density on these steels is ioFe +3/Fe+2=0.1 A/cm2 independent of concentrations of Fe+3 and Fe+2 and that the reduction reactions under activation control with bc=0.100V/dec. (b) One might conclude from (a) that extremely low concentrations of Fe+3 and Fe+2 will passivate stainless steels. Will this always be true? Explain Why
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