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A brass and unknown metallic material were placed in aerated % 3 . 5 NaCl solution until steady - state corrosion potentials were reached. Then

A brass and unknown metallic material were placed in aerated %3.5NaCl solution
until steady-state corrosion potentials were reached. Then they were coupled with conductive
wire. Measured galvanic currents are given in the table below.
a) Identify the unknown material, by using the Ecorr datas and the series of galvanic chart, and
predict the corrosion potential of unknown material
b) Which material did corrode in galvanic couple? Why?
c) Calculate corrosion current density in galvanic couple as a function of Ac/Aa ratio. How
would the corrosion rate will change as a function of Ac/Aa ratio? Answer without
calculation of the corrosion rate)
d) Explain the results in the part (b) by schematically drawing the E vs. Log I before and
after galvanic coupling for your system. Show ECor and EGal.Cor values on the graph with
corrosion currents for uncouple materials and couple materials.
e) For your galvanic couple, indicate the possible oxidation (anodic) and reduction
(cathodic) reactions before and after connecting (galvanic coupling). Where are the major
anodic and cathodic reactions taking place after galvanic coupling?
E Cor-Brass =-0.227V Delta Cor-Brass - E Cor-X
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