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A liquid solution containing 0 . 9 kmol H 2 SO 4 and 6 . 8 kmol H 2 0 at 3 1 1 .

A liquid solution containing 0.9 kmol H2SO4 and 6.8 kmol H20 at 311.15 K (38C) absorbs 0.45 kmol of S03(g), also at 311.15 K (38 deg * C) forming a more concentrated sulfuric acid solution. If the process occurs isothermally, determine the heat transferred. Data: AH/SO-395720 J/mol; AHfH,O-285830 J/mol; Delta*Hf*H_{2}*S*O_{4}=-813989 J/mol and Refer H-x diagram for H2S04/H20 for the required data.
10/14
700
600
400
100
Vapor
200
Bolling Ine
100
0
-100
SOLID
-200
SOLO
-300
400
-500
10
20
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50
00
100
mass50
Fig: Hx diagram for H2S04/H20

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