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A model polyethylene is prepared by hydrogenating a narrow distribution 1 , 4 - polybutadi - ene prepared by anionic polymerization. If the polymerization yields

A model polyethylene is prepared by hydrogenating a narrow distribution 1,4-polybutadi-
ene prepared by anionic polymerization. If the polymerization yields 8% "vinyl" addition,
what would you estimate for the equilibrium melting point of the resulting polyethylene? It
might be helpful to think of this as a random copolymer, and consider the mole fraction of
"defects" represented by the side groups, on a per ethylene backbone unit basis. Equation
13.4.12 may also be relevant.
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