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A model polyethylene is prepared by hydrogenating a narrow distribution 1 , 4 - polybutadi - ene prepared by anionic polymerization. If the polymerization yields
A model polyethylene is prepared by hydrogenating a narrow distribution polybutadi
ene prepared by anionic polymerization. If the polymerization yields "vinyl" addition,
what would you estimate for the equilibrium melting point of the resulting polyethylene? It
might be helpful to think of this as a random copolymer, and consider the mole fraction of
"defects" represented by the side groups, on a per ethylene backbone unit basis. Equation
may also be relevant.
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