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A saturated solution of naphthalene in chlorobenzene is prepared at a temperature of 2 9 3 K and a pressure of 1 . 0 0
A saturated solution of naphthalene in chlorobenzene is prepared at a temperature of K and a pressure of bar. Under these conditions, the mole fraction of naphthalene is xsat The pressure is raised to bar at constant temperature, and some naphthalene precipitates out. Derive an equation for the mole fraction of naphthalene still in solution at a pressure of bar we will call it x Your final answer should provide an equation for x in terms of xsat, the change in pressure, the molar volume of naphthalene solid VNs and the partial molar volume of naphthalene in the liquid at bar.
Assume ideal solution behavior and that the molar volume of naphthalene in chlorobenzene is independent of pressure. HINT: show the work to get x xsatexpDelta PVNs VNRT where VN is partial molar volume
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