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A solution is prepared with 0.7mMNa2CO3,0.5mMNH4OH and 120mMK2SO4. Assume that the K2SO4 completely dissociates into K+and SO42 and that these ions dominate the ionic strength.
A solution is prepared with 0.7mMNa2CO3,0.5mMNH4OH and 120mMK2SO4. Assume that the K2SO4 completely dissociates into K+and SO42 and that these ions dominate the ionic strength. (Assume no H2SO4 or HSO4in solution.) Give 3 significant digits on each numerical answer below. [5 points each] 1. Calculate the value of cKw and the cKa constants that are relevant to the first two species added to this solution. 2. Find the pH of this solution that would be measured by a pH probe. (Note that you solved a similar problem in the Module 4-2 assignment.) 3. Calculate the precise alkalinity, i.e., the exact concentration of strong acid that would need to be added to result in a pH meter reading 4.5. (Neglect any change in ionic strength resulting from the titrant.) 4. What is the exact ionic strength of the initial solution based on your calculated speciation (from question 2), and how close is it to the approximation that you used in question 1? What accounts for the difference
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