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A stationary spherical particle composed of species A with radius R ( t ) is surrounded by a liquid of infinite extent. Initially, the particle

A stationary spherical particle composed of species A with radius R(t) is surrounded by a liquid
of infinite extent. Initially, the particle has radius R0 and the liquid is pure species B. For t>0,
the solid dissolves in the liquid and the mole fraction of A at the solid-liquid interface (r=R) is
xAe. The molar density of the liquid c and diffusivity DAB are constant and there are no chemical
reactions. The molar density of the particle is ?bar(c)~~c. The mole fraction of A in the liquid has
the form xA=xA(r,t) and molar-average velocity has the form vr**=vr**(r,t),v**=v**=0.
(a)10 pts Use the molar forms of the continuity equation and jump balance for mass to show
that vr**(r,t)=0.
(b)10pts Write the differential equation that governs xA(r,t).
(c)5 pts Write the boundary conditions for xA.
(d)5 pts Solve the differential equation in (b) assuming the quasi-steady state approximation
is valid to obtain an expression for xA(r,t).
(e)10 pts Write the differential equation that governs R(t).
(f)5 pts Apply the 'n-m rule' to this problem and identify the dimensionless parameter(s)
that govern the problem.
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