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A stationary spherical particle composed of species A with radius R ( t ) is surrounded by a liquid of infinite extent. Initially, the particle
A stationary spherical particle composed of species A with radius is surrounded by a liquid
of infinite extent. Initially, the particle has radius and the liquid is pure species For
the solid dissolves in the liquid and the mole fraction of at the solidliquid interface is
The molar density of the liquid and diffusivity are constant and there are no chemical
reactions. The molar density of the particle is ~~ The mole fraction of in the liquid has
the form and molaraverage velocity has the form
a pts Use the molar forms of the continuity equation and jump balance for mass to show
that
b Write the differential equation that governs
c pts Write the boundary conditions for
d pts Solve the differential equation in b assuming the quasisteady state approximation
is valid to obtain an expression for
e pts Write the differential equation that governs
f pts Apply the rule' to this problem and identify the dimensionless parameters
that govern the problem.
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