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A voltaic cell consists of a Z n Z n 2 + half - cell and a N i N i 2 + half -

A voltaic cell consists of a ZnZn2+ half-cell and a NiNi2+ half-
cell at 25C. The initial concentrations of Ni2+ and Zn2+ are 1.60
molL-1 and 0.100molL-1, respectively.
Zn2+(aq)+2e-Zn(s),E=-0.76V
Ni2+(aq)+2e-Ni(s),E=-0.23V
What is the initial cell potential?
Express your answer to two decimal places and include the appropriate units.
Part B
What is the cell potential when the concentration of Ni2+ has fallen to 0.600molL-1? Assume that both half-cells have the same volume.
Express your answer to two decimal places and include the appropriate units.
Ecell=,
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Part C
What are the concentrations of Ni2+ and Zn2+ when the cell potential falls to 0.46V?
Express your answers using two significant figures separated by a comma.
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