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a)A possible mechanism for the reaction 2NO+O22NO2 is 1.NO+NON2O22.N2O23.N2O2+O22NOk1k2k3 i) Apply steady state approximation to obtain a rate laux in terms of concentration of NO

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a)A possible mechanism for the reaction 2NO+O22NO2 is 1.NO+NON2O22.N2O23.N2O2+O22NOk1k2k3 i) Apply steady state approximation to obtain a rate laux in terms of concentration of NO and O2 ii) If only a very small fraction of all N2O2 formed goes to give product in Eqn. (2) and If the activation energies E1=82kJ/mol,E2=95kJ/mol,E3=82kJ/mol, What is the observed activation energy. b) Consider the following mechanism to describe the overall reaction. A+BD Mechanism: kl 1. step 2AA2k1 k2 2. step A+Bk2C K2=k2k2 3. step A2+Ck3D+2A slow What is the rate equation derived from above mechanism. a)A possible mechanism for the reaction 2NO+O22NO2 is 1.NO+NON2O22.N2O23.N2O2+O22NOk1k2k3 i) Apply steady state approximation to obtain a rate laux in terms of concentration of NO and O2 ii) If only a very small fraction of all N2O2 formed goes to give product in Eqn. (2) and If the activation energies E1=82kJ/mol,E2=95kJ/mol,E3=82kJ/mol, What is the observed activation energy. b) Consider the following mechanism to describe the overall reaction. A+BD Mechanism: kl 1. step 2AA2k1 k2 2. step A+Bk2C K2=k2k2 3. step A2+Ck3D+2A slow What is the rate equation derived from above mechanism

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