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Aluminum - lithium alloys are well known in the aerospace industry as strong, light - weight materials for advanced aircraft structures. However, these alloys have

Aluminum-lithium alloys are well known in the aerospace industry as strong, light-weight materials for
advanced aircraft structures. However, these alloys have also been considered as electrodes in Li-ion
batteries. The standard reduction potentials for Al and Li are:
Al3++3e-Al,V0=-1.677vs. NHE
Li++e-Li,V0=-3.040vs. NHE
Thus, in an electrochemical cell with Al metal and Li metal as the two electrodes, lithium will serve as
the anode and aluminum the cathode, with the cathodic reaction written generally as:
Al+xLi++xe-LixAl
(a) Using the Al-Li phase diagram* to determine the phase evolution of the discharge, determine the
expected discharge voltage profile if the reaction was performed at 150C. Make a sketch and label it.
Weight Percent Lithium
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