answer for 22.58, 15.26, 22.59

a. The allyl anion has a nonbonding electron pair on the allylic carbon: allyl anion This anion has two more electrons than the allyl cation. Use the molecular orbital diagram in Eig. 15.14b to decide which molecular orbital these "extra electrons" occupy. b. According to the molecular orbital description, which carbons of the allyl anion bear the negative charge? c. Show that the same conclusion can be reached by drawing resonance structures of the allyl anion. Use the curved-arrow notation. a. Show that the two following compounds have the same conjugate base. b. Which compound is more acidic? Explain your reasoning using an argument invoking the relative free energies of A and B. a. Draw the structure of the conjugate base of each of the following compounds. What is the relationship between the two conjugate bases