Question
Apply example 13.1 in the textbook for a range of compositions listed as 0.0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, and 1.0
Apply example 13.1 in the textbook for a range of compositions listed as 0.0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, and 1.0 and plot the points on a graph of P vs. composition and T vs. composition.For the system methanol(1)/methyl acetate(2), the following equations provide a reasonable correlation for the activity coefficients:ln 1 = Ax2 and ln 2 = Ax1 , where A = 2.771 0.00523*TIn addition, the following Antoine equations provide vapor pressures:ln P1sat = 16.59158 3643.31 /(T-33.424) and ln P2sat = 14.25326 2665.54/(T 53.424),where T is in Kelvins and the vapor pressures are in kPa. Assuming the validity of Eq. (13.19) given as:yiP = xi iPisat (i = 1, 2, . . . , N), calculate and plot the phase diagrams for:(a) (22 pts) P and {yi} for T = 318.15 K and x1 = 0:0.1:1.0. Plot on P vs. composition graph.(b) (22 pts) P and {xi} for T = 318.15 K and y1 = 0:0.1:1.0. Plot on P vs. composition graph.(c) (22 pts) T and {yi} for P = 101.33 kPa and x1 = 0: 0.1:1.0. Plot on T vs. composition graph.(d) (22 pts) T and {xi} for P = 101.33 kPa and y1 = 0:0.1:1.0. Plot on T vs. composition graph.(e) (12 pts) The azeotropic pressure and the azeotropic composition for T = 318.15 K if there exists any and indicate these points on the phase diagram
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