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At the Toormina (NSW) water treatment plant, raw water undergoes treatment by rapid sand filtration. Under normal circumstances, filtered water is then disinfected by
At the Toormina (NSW) water treatment plant, raw water undergoes treatment by rapid sand filtration. Under normal circumstances, filtered water is then disinfected by chlorination to achieve a free hypochlorous acid (HOCI) CT of 45.0 mg.L-1.min at pH 6.0. The chlorine contact tank has a volume of 1550 m. Chlorination is normally achieved using 1-ton cylinders of compressed (liquified) chlorine. However, in emergency circumstances, the plant relies instead upon a supply of sodium hypochlorite solution, which can be dosed directly into the chlorine contact tank. Sodium hypochlorite solution has a concentration 12.5% available chlorine (by mass). The standard operating procedure stipulates that the sodium hypochlorite solution should be added to filtered water at a rate of 1 part in 25,000 (for example, 1 kg sodium hypochlorite solution in 25,000 kg of water). Following sodium hypochlorite dosing, online monitoring indicates a change in pH to pH 8.2 and no additional adjustments are made. Assume: Density of water is 1000 kg.m-3. HOCI HOCI pKa = 7.5 Hypchlorite ion has negligible (zero) disinfection strength, compared to hypochlorous acid. After dosing sodium hypochlorite solution in accordance with the standard operating procedure, determine: (a) The concentration of total available chlorine in the chlorine contact tank (mg/L) (5 marks) (b) The concentration of hypochlorous acid in the chlorine contact tank (5 marks) (c) The maximum treated water production rate (m.hour) to maintain satisfactory disinfection (5 marks)
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