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cab you help me with 2 and 3 INTRODUCTION In this lab we will synthesize the compound cyclohexa-1,4-diene-1,2-dicarboxylic acid dimethyl ester, using the classic Diels-Alder
cab you help me with 2 and 3
INTRODUCTION In this lab we will synthesize the compound cyclohexa-1,4-diene-1,2-dicarboxylic acid dimethyl ester, using the classic Diels-Alder (4+2) cycloaddition reaction, starting with 1,3-butadiene as the diene, and butynedioic acid dimethyl ester as the dienophile. Once synthesized, you will characterize the substituted cycloalkene product by infrared (IR) spectroscopy and nuclear magnetic resonance (NMR) spectroscopy to confirm that you actually synthesized what you set out to create. BACKGROUND German chemists Otto Diels and Kurt Alder first described the organic reaction that now bears their names in 1928, and earned them the Nobel Prize in Chemistry in 1950. In this reaction, a conjugated diene will react with a dienophile, if an appropriate electron-withdrawing group is attached to the dienophile, to produce an adduct containing two new o bonds. This is important, because the synthesis of new C-C bonds is relatively difficult, and because the products of Diels-Alder reactions containing cyclohexene rings can be used in other reactions form complex molecular structures. er of curloaddition reactions ed due date. Canvas as a pdf, along with the 1. (2 pts) Draw the mechanism for the reaction in this lab, and include the structure of the expected major product. uta - . och, octa 2. (2 pts) Draw the complete labeled t MO diagrams for both reactants, and identify the HOMO and LUMO for both. Lumo 181818 818 Slots 1874-88 888 je 18 616 348 od antiff 181818yn. rym 18 18 28 13 for us symo 8 8 8 4 MO 000 ant 11 Juno 88% 89% 885 88 3. (1 pt) Identify a structural feature of the alkyne reactant used in this lab that increases the reaction rate of this Diels-Alder reaction. How does this structural feature increase the Diels-Alder reaction rate Step by Step Solution
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