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Calcium hydroxide dissolves into water as Ca+ and OH+ ions. The solubility of calcium hydroxide, Ca(OH)2, at 25C was measured to be 1.52 g per
Calcium hydroxide dissolves into water as Ca+ and OH+ ions. The solubility of calcium hydroxide, Ca(OH)2, at 25C was measured to be 1.52 g per kg of water. Calculate the corresponding Ksp of Ca(OH)2 by: a) assuming ideal behavior and b) by using calculated activities according to the Extended Debye-Hckel Equation. Use these values to generate corresponding estimates for the Standard Change in Free Energy, AGrxn, of the Ca(OH)2 dissolution reaction. Use the following Standard Free Energy of Formation data to calculate the accepted value for the Standard Change in Free Energy of the reaction and the relative errors of your previously calculated value: Species State AG 298 S298 /J moll /J mol! /J mol K- Ca2+ aq -553,427 -542,740 -53.14 Ca(OH)2 -898,468 -986,085 83.39 OH aq -157,248 -229,987 -10.88 Assume that the hydration numbers of Ca2+ and OH' are 6 and 4, respectively. S
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