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Calculation task: Thermodynamics A number of properties of gas-liquid equilibrium at 1 bar for morpholine are desired to be estimated. Data for estimating these properties
Calculation task: Thermodynamics A number of properties of gas-liquid equilibrium at 1 bar for morpholine are desired to be estimated. Data for estimating these properties must be found from the following information: log10(Psat)=A+TB+Clog10(T)+DT+ET2 Where P is the vapor pressure given in mmHg T is the temperature in Kelvin A=23.4107B=2891.2C=5.1633D=1.9719109E=7.3526107 Critical values are Pc=53.4barTc=618KVc=276cm3mol1Zc=0.287=0.474 a. From the expression for the vapor pressure, calculate the boiling point temperature for morpholine at 1 bar. b. Calculate the molar volume for morpholine from the van der Waal equation as saturated vapor and as saturated liquid (equilibrium between vapor and liquid) at 1 bar. c. Rewrite the expression for vapor pressure into form of: In(Psat)=a+Tb+cIn(T)+dT+eT2 Where P is the vapor pressure given in Pa and T is the temperature in Kelvin and enter the values for a,b,c,d, and e. d. Calculate from the Clapeyron equation the enthalpy of vaporization for morpholine at 1 bar. e. At equilibrium between a pure vapor and liquid, the Gibbs free energy is the same for the vapor and the liquid. Based on this information and the value for the enthalpy of evaporation determined in Task (d) calculate the entropy change during evaporation
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