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Consider a desorption process in a spherical sample. Initially, the sphere has uniform species A mass fraction w A 0 and radius R ; for

Consider a desorption process in a spherical sample. Initially, the sphere has uniform species A mass
fraction wA0 and radius R; for t>0, the species A mass fraction at the surface of the sphere is
maintained at wAeq. Assuming is constant and that R is approximately constant, write in dimensionless
form the evolution equation for wA with the opportune initial and boundary conditions. Derive a
solution for the obtain partial differential equation using the change of variable u=rwA.
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