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Consider a reversible elementary aqueous reaction: A2R. It is found that the reaction has the standard Gibbs free energy (G) of 4406J/mol and standard enthalpy

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Consider a reversible elementary aqueous reaction: A2R. It is found that the reaction has the standard Gibbs free energy (G) of 4406J/mol and standard enthalpy of reaction (H) of 41570J/mol at 25C. The specific heats (cp) of A and R are 1000J/mol.K and 600J/mol.K, respectively. Note that this is elementary reversible reaction and the given initial conditions are: CAO=1mol/L and CAO=0mol/L in the batch reactor. Also the Arrhenius temperature dependency of the forward reaction rate constant is given by k=exp(14.257T5424.6) a) Sketch the equilibrium conversion vs. temperature curve of the reaction between 0C and 100C. What restrictions should be placed on the reactor operating isothermally if we are to obtain a conversion of %50 or higher? b) Prepare the conversion-temperature chart with reaction rate as parameter (Reaction rate: (rA=0.001);(rA=0.005);(rA=0.01);(rA=0.02);(rA=0.05);(rA=0.1)) Consider a reversible elementary aqueous reaction: A2R. It is found that the reaction has the standard Gibbs free energy (G) of 4406J/mol and standard enthalpy of reaction (H) of 41570J/mol at 25C. The specific heats (cp) of A and R are 1000J/mol.K and 600J/mol.K, respectively. Note that this is elementary reversible reaction and the given initial conditions are: CAO=1mol/L and CAO=0mol/L in the batch reactor. Also the Arrhenius temperature dependency of the forward reaction rate constant is given by k=exp(14.257T5424.6) a) Sketch the equilibrium conversion vs. temperature curve of the reaction between 0C and 100C. What restrictions should be placed on the reactor operating isothermally if we are to obtain a conversion of %50 or higher? b) Prepare the conversion-temperature chart with reaction rate as parameter (Reaction rate: (rA=0.001);(rA=0.005);(rA=0.01);(rA=0.02);(rA=0.05);(rA=0.1))

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