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Consider the case of several species (AI... An) adsorbing on a uniform surface. K + 4 42 + A + n * * *
Consider the case of several species (AI... An) adsorbing on a uniform surface. K + 4 42 + A + n * * * 4* +4 K * n 4 * A n (a) Derive expressions for the fractional coverage of the surface intermediates. (b) Now, let's assume there are only 2 species that adsorb onto the surface to form surface intermediates, and that they react on the surface to form a product P. * P+2* Consider the case of low pressures, where the concentration of surface intermediates is small. Given a constant total pressure, i.e. (A1) + (A2) = constant, what should the ratio B=(A1)/(42) be to maximize the rate of the reaction?
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Elementary Principles of Chemical Processes
Authors: Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
4th edition
978-1118431221, 9781119192138, 1118431227, 1119192137, 978-1119498759
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