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( d ) The measured molar heat capacity at constant volume, C v for a monatomic gas ( helium , H e ) and a

(d) The measured molar heat capacity at constant volume, Cv for a monatomic gas (helium,He) and a diatomic gas (nitrogen,N2) at around room temperature and pressure are 12.5J mole K-1 and 20.8Jmole-1, respectively. Explain why the experimental value of CV for the diatomic molecule is lower than the estimated value whereas the experimental value of CV is close to the calculated value for the monatomic molecule. Under what conditions will the measured CV be close to the calculated (classical) value?

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