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Describe how the application of a potential more negative that the equilibrium potential can facilitate the reduction of Cu 2 + at a carbon electrode

Describe how the application of a potential more negative that the equilibrium potential can facilitate the reduction of Cu2+ at a carbon electrode immersed in in an electrolyte. Use an appropriate diagram in your answer.
A solution consists of 1.0 M Co(NO3)2 and 1.0 M Cu(NO3)2. Eo Co2+/Co =0.28 V (vs SHE)
Eo Cu2+/Cu =+0.34 V (vs SHE)
R =8.3143 J K1 mol1, F =98485 C mol1
(ii) In a cathodic deposition experiment at 298 K, which species, Co2+ or Cu2+, would
you expect to deposit first? Explain your answer.
(iii) What potential range would you use to separate the Cu2+ from the Co2+?
(iv) Using an appropriate calculation, show that it is indeed possible to separate the Co2+ from the Cu2+.

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