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Describe how the application of a potential more negative that the equilibrium potential can facilitate the reduction of Cu 2 + at a carbon electrode
Describe how the application of a potential more negative that the equilibrium potential can facilitate the reduction of Cu at a carbon electrode immersed in in an electrolyte. Use an appropriate diagram in your answer.
A solution consists of M CoNO and M CuNO Eo CoCo V vs SHE
Eo CuCu V vs SHE
R J K mol F C mol
ii In a cathodic deposition experiment at K which species, Co or Cu would
you expect to deposit first? Explain your answer.
iii What potential range would you use to separate the Cu from the Co
iv Using an appropriate calculation, show that it is indeed possible to separate the Co from the Cu
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