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Describe the autoacceleration and autodeceleration processes in radical polymerizations and how they are affected by crosslinking, the presence / amount of a solvent and temperature.
Describe the autoacceleration and autodeceleration processes in radical
polymerizations and how they are affected by crosslinking, the presenceamount
of a solvent and temperature. Specifically, discuss how the overall rate of
polymerization, the conversion at which autoaccelerationautodeceleration begins
and the final overall conversion are qualitatively changed by i addition of
crosslinking agents in higher concentrations, ii addition of solvent, and iii
temperature. iv Explain why autoacceleration generally does not occur in ionic
polymerizations but autodeceleration still does.
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