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Describe the autoacceleration and autodeceleration processes in radical polymerizations and how they are affected by crosslinking, the presence / amount of a solvent and temperature.

Describe the autoacceleration and autodeceleration processes in radical
polymerizations and how they are affected by crosslinking, the presence/amount
of a solvent and temperature. Specifically, discuss how the overall rate of
polymerization, the conversion at which autoacceleration/autodeceleration begins
and the final overall conversion are qualitatively changed by (i) addition of
crosslinking agents in higher concentrations, (ii) addition of solvent, and (iii)
temperature. (iv) Explain why autoacceleration (generally) does not occur in ionic
polymerizations but autodeceleration still does.
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