Question
Draw and explain the mechanism for the possible structural fragments and give its corresponding m/z value while analyzing the molecular structure given. A. McLafferty rearrangement
Draw and explain the mechanism for the possible structural fragments and give its corresponding m/z value while analyzing the molecular structure given.
A. McLafferty rearrangement of ketone
B. Homolytic alpha-cleavage of ketone
C. Homolytic alpha-cleavage of ether (There are 2 possible fragments for this)
D. Gamma-cleavage of alcohol (loss of water)
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Undergraduate Instrumental Analysis
Authors: James W Robinson, Eileen M Skelly Frame, George M Frame, George M Frame II
6th Edition
0824753593, 9780824753597
