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El 1-butanol y el clorobenceno forman un sistema azeotrpico de punto de ebullicin mnimo. La fraccin molar de 1-butanol en las fases lquida (x) y

El 1-butanol y el clorobenceno forman un sistema azeotrpico de punto de ebullicin mnimo. La fraccin molar de 1-butanol en las fases lquida (x) y vapor (y) a 1.000 atm se da a continuacin para una variedad de temperaturas de ebullicin.

T/K 396.57 393.94 391.60 390.15 389.03 388.66 388.57

x0,1065 0.17 0.2646 0.3687 0.5017 0.6091 0.7171

Y 0.2859 0.3691 0.4505 0.5138 0.5840 0.6409 0.7070

El clorobenceno puro hierve a 404,86 K. (a) Construya la porcin rica en clorobenceno del diagrama de fase a partir de los datos. (b) Estime la temperatura a la cual comienza a hervir una solucin cuya fraccin molar de 1-butanol es 0.300. (c) Indique las composiciones y proporciones relativas de las dos fases presentes despus de que una solucin inicialmente 0.300 1-butanol se calienta a 393.94 K

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