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Ethyl acetate is an extensively used solvent and can be formed by the vapor - phase esterification of acetic acid and ethanol. C H 3

Ethyl acetate is an extensively used solvent and can be formed by the vapor-phase esterification of acetic
acid and ethanol.
CH3-CO-OOH+CH3CH2OHlongrightarrowCH3-CO-OCH2CH3+H2O
The reaction was studied using a microporous resin as a catalyst in a packed-bed microreactor [Ind. Eng.
Chem. Res., 26(2),198(1987)]. The reaction is first order in ethanol and pseudo zeroth order in acetic
acid (-rA=kCA). The total volumetric feed rate is 25dm3min, the initial pressure is 10atm, the
temperature is 223C, and the pressure drop parameter, , is 0.01kg-1. For an equimolar feed rate of
acetic acid and ethanol, the specific reaction rate is roughly 1.3dm3kgcat*min.
a. Calculate the maximum weight of catalyst that one could use and maintain an exit pressure
above 1atm.
b. Write out the CRE algorithm and then solve these equations analytically to determine the catalyst
weight necessary to achieve 90% conversion.
c. Write a python program to plot and analyze conversion (x), pressure ratio (p=PP0), and
volumetric flowrates (vv0) as a function of catalyst weight down the packed-bed reactor.
d. Neglecting pressure drop, re-analyze x as a function of catalyst weight down the packed-bed
reactor. How does this result compare with part c.?
e. How would the conversion from part c. be affected if we pack the catalyst with the same density
and total weight in a longer reactor with half the pipe diameter?
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