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Ethyl acetate is used as a solvent for the extraction of caffeine from coffee beans in a membrane extraction unit. A key parameter that determines

Ethyl acetate is used as a solvent for the extraction of caffeine from coffee beans in a membrane extraction unit. A key parameter that determines the peformance of such a unit is the rate of transport of caffeine across the membrane. In a laboratory set up (see Figure),
caffeine solution and ethyl acetate are separated by a porous membrane. Caffeine diffuses through the mebrane pores and is dissolved in ethyl acetate. Therefore, concentration of caffeine in water (CF) decreases, while caffeine concentration in ethyl acerate (CP) increases with time. The rate of diffusion of caffeine across the membrane (R) can be expressed by:
R=KA(CF-CP)
Where K is the overall mass transfer coefficient and A is the membrane area. The volume of water phase (VF) and the volume of ethyl acetate phase (VP) remain constant during the extraction process and both phases are fully mixed. Initially (att=0), the concentration of caffeine in water is CFo and ethyl acetate has no caffeine (CPo=0) :
a) Write caffeine balances for the water phase (Feed) and for the ethyl acetate phase (Permeate) and show that the differential equations describing this system are given by:
dCFdt=(CF-CP)
dCPdt=(CF-CP)
Where and are constants that depend on known parameters, ie A,K,VP, and VF.
b) Using D-operator, solve the above system of ODEs to obtain an expression for the concentration of caffeine in permeate as a function of time, CP(t).
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