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Experimental vs . simulated P . S . Whitfield et al . , Solid State lonics 1 8 1 ( 2 0 1 0 )

Experimental vs. simulated
P.S. Whitfield et al., Solid State lonics 181(2010)740 suggested the following phase
diagram
Fig. 5. Composition/temperature phase diagram for the succinonitrile:LiTFSI system
heated from -100C constructed from the XRD data.
Top plot is from experimental data. 2 plots below is from simulation. Mol% is of the LiTSFI
content in solid solutions (LiTFSI)x(SN)1-x. How the Li+ ionic conductivity varies with
composition over this range. Based on these simulations, which (LiTFSI)x(SN)1-x
composition would you suggest as a fast-ion conducting solid electrolyte for battery
applications.
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