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For a linear polymer molecule, the total chain length L depends on the bond length between chain atoms d, the total number of bonds in
For a linear polymer molecule, the total chain length L depends on the bond length between chain atoms d, the total number of bonds in the molecule N, and the angle between adjacent backbone chain atoms , as follows: 0 L = Nd sin (9) (14.11) Furthermore, the average end-to-end distance for a series of polymer molecules r is equal to: r = For a linear polytetrafluoroethylene determine: (a) the number-average molecular weight for L= 1000 nm; M = Mn i M = Mn = dN (b) the number-average molecular weight for r = 13 nm. T. g/mol g/mol (14.12)
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