Answered step by step
Verified Expert Solution
Link Copied!

Question

1 Approved Answer

For the hjydlogen atom (using atomic units) the ground state energy s E = _? and the (unnormalized) ground state wavetunction is '(r) s e

image text in transcribed
For the hjydlogen atom (using atomic units) the ground state energy s E = _? and the (unnormalized) ground state wavetunction is '(r) s e a) For W (r) =", calculate H;; and S;; and get E; = H;;/Sy;. b) For Wy(r) = ", calculate H, and S and get E> = Hx/So. ) For (r) = \\W:i(r) + ;'Wa(r) where ; and , are variational parameters, what is E for the optumum values of ; and ,? Note: For part ) you will need to calculate Hi and Si (you already have Hii, S11, H, and S;) and you will need to construct the 2 2 determinant to get the quadratic equation to solve for E (choosing the more negative root). In atomic units, the potential | g : energy operator 1s and the kinetic energy operator is r ~1d 2r drl mn all your integrals. | Make sure to include the 1 from the volume element J"rad_n"r n+l

Step by Step Solution

There are 3 Steps involved in it

Step: 1

blur-text-image

Get Instant Access to Expert-Tailored Solutions

See step-by-step solutions with expert insights and AI powered tools for academic success

Step: 2

blur-text-image

Step: 3

blur-text-image

Ace Your Homework with AI

Get the answers you need in no time with our AI-driven, step-by-step assistance

Get Started

Recommended Textbook for

Advanced Quantum Mechanics Materials And Photons

Authors: Rainer Dick

2nd Edition

3319256750, 9783319256757

More Books

Students also viewed these Physics questions

Question

How can a company improve its acid-test ratio?

Answered: 1 week ago

Question

What is the cycle of intimate partner abuse?

Answered: 1 week ago