Answered step by step
Verified Expert Solution
Link Copied!

Question

1 Approved Answer

For the hydrogen atom (using atomic units) the ground state energy -1 2 is E = and the (unnormalized) ground state wavefunction is Y(r)

image

For the hydrogen atom (using atomic units) the ground state energy -1 2 is E = and the (unnormalized) ground state wavefunction is Y(r) =e a) For Y(r) = 0.5, calculate H1 and S11 and get E = H1/S11. -2.0r b) For Y(r) =e0r, calculate H22 and S22 and get E = H22/S22. = E2 c) For Y(r) c(1) c22(r) where c and c are variational parameters, what is E for the optimum values of c and c? Note: For part c) you will need to calculate H12 and S12 (you already have H11, S11, H22, and S22) and you will need to construct the 2 2 determinant to get the quadratic equation to solve for E (choosing the more negative root). In atomic units, the potential energy operator is 7 and the kinetic energy operator is 2. Make sure to include the r from the volume element -1 d 2r dr d dr in all your integrals. -1 00 Fredr 0 = n! n+1

Step by Step Solution

There are 3 Steps involved in it

Step: 1

blur-text-image

Get Instant Access to Expert-Tailored Solutions

See step-by-step solutions with expert insights and AI powered tools for academic success

Step: 2

blur-text-image

Step: 3

blur-text-image

Ace Your Homework with AI

Get the answers you need in no time with our AI-driven, step-by-step assistance

Get Started

Recommended Textbook for

Probability & Statistics For Engineers & Scientists

Authors: Ronald E. Walpole, Raymond H. Myers, Sharon L. Myers, Keying

7th Edition

9789813131279, 130415294, 9813131276, 978-0130415295

More Books

Students also viewed these Physics questions