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From High surface area carbon from polyacrylonitrile for high - performance electrochemical capacitive energy storage by Gupta answer the following ( a ) The authors
From High surface area carbon from polyacrylonitrile for highperformance electrochemical capacitive energy storage by Gupta answer the following
a The authors report a specific capacitance for the high surface area mg sample APAN of Fg at Ag current density in the pure EMIMBF electrolyte see orange curves in Graphs bc What is the approximate time constant for charging the double layer for electrochemical capacitors made from APAN and using the EMIMBF electrolyte? Assume that a micron thick separator was used in the experiments, the mass of APAN is g and estimate the resistance of the electrolyte from the ohmic drop in Graph b
b The authors use electrochemical impedance spectroscopy EIS to compare the properties of the APAN samples with the AC sample. How do they determine that AC has higher electrical conductivity but lower ion diffusivity than APAN The Nyquist plots are the second set of graphs
Figure Sa Nyquist plots of symmetric configuration supercapacitors for AC and APAN in different electrolytes:
in acetonitrile and pure b Nyquist plots of commercial AC and APAN in Li half cells.
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