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From High surface area carbon from polyacrylonitrile for high - performance electrochemical capacitive energy storage by Gupta answer the following ( a ) The authors

From High surface area carbon from polyacrylonitrile for high-performance electrochemical capacitive energy storage by Gupta answer the following
(a) The authors report a specific capacitance for the high surface area (3550 m2/g) sample A-PAN of 150 F/g at 1 A/g current density in the pure EMIMBF4 electrolyte (see orange curves in Graphs 2b-c). What is the approximate time constant for charging the double layer for electrochemical capacitors made from A-PAN and using the EMIMBF4 electrolyte? Assume that a 50 micron thick separator was used in the experiments, the mass of A-PAN is 1 g, and estimate the resistance of the electrolyte from the ohmic drop in Graph 2b.
(b) The authors use electrochemical impedance spectroscopy (EIS) to compare the properties of the A-PAN samples with the AC sample. How do they determine that AC has higher electrical conductivity but lower ion diffusivity than A-PAN? The Nyquist plots are the second set of graphs
Figure S1.(a) Nyquist plots of symmetric configuration supercapacitors for AC and A-PAN in different electrolytes: 1MEMIMBF4
in acetonitrile and pure EMIMBF4.(b) Nyquist plots of commercial AC and A-PAN in Li half cells.
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