Given that H=U+PV : a. show that the molar heat capacities Cp and Cv are related by Cp=Cv+R for an ideal gas. b. Use Cp=CV+R to obtain an expression for CV for a gas that behaves approximately ideal having a heat capacity temperature dependence of Cp=0.06436R+(2.137102K1)RT(8.263106K2)RT2+(1.024109K3)RT3. The approximately ideal gas from Problem 4 is heated from 25 to 1000C. Citing clear reasons/explanations for how you arrive at expressions, calculate values for w,q,U and H for heating at a. constant pressure. b. constant volume