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Given that the structure of 11-cis retinal and all-trans retinal are chemically the same molecule, why is it possible to optimize their structures independently? In

Given that the structure of 11-cis retinal and all-trans retinal are chemically the same molecule, why is it possible to optimize their structures independently? In other words, why doesn't optimization of the higher energy form lead to the lower energy form? Draw a simple potential energy diagram to help explain.

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