Answered step by step
Verified Expert Solution
Link Copied!

Question

1 Approved Answer

Hello, I was able to get pretty far in my homework, but I need help figuring out this last question. Question: The pKa for any

Hello, I was able to get pretty far in my homework, but I need help figuring out this last question.

Question: The pKa for any weak acid can be determined from the Henderson Hasselbalch Equation pH = pKa + log [A- ] [HA]. Notice that this equation is like that for a straight line; y = mx + b. Using data from our table, we can take advantage of this fact to find an estimate for the pKa of p-nitrophenol.

For example, if we make the following substitutions: y = pH m = slope of the line = 1.0 (each increase in pH represents a directly proportional increase in log [A- ]/[HA] x = log [A- ]/[HA] b = pKa Then we can estimate the pKa for p-nitrophenol from a graph of pH versus log [A- ]/[HA] Prepare a second graph (Figure 2) of pH (y-axis) versus log [A- ]/[HA] (x-axis) using the values from Table 1. Use the scatter plot option in Microsoft Excel or similar and produce a line of best fit (regression) through the data points.

pH Absorbance [A-] (mM) [HA] (mM) log [A-]/[HA]
9.0 0.516 0.00004mM 0mM N/A
8.0 0.409 4.09 X 10^-4mM 1.82 X 10^-4 1.63
7.5 0.308 3.08 X 10^-4 1.71 X 10^-4 -0.52
7.0 0.256 2.56 X 10^-4 7.11 X 10^-5 -0.6
6.5 0.108 1.08 X 10^-4 1.57 X 10^-5 -1.3
6.0 0.007 7.0 X 10^-7 1.9 X 10^-8 -3.5

Step by Step Solution

There are 3 Steps involved in it

Step: 1

blur-text-image

Get Instant Access to Expert-Tailored Solutions

See step-by-step solutions with expert insights and AI powered tools for academic success

Step: 2

blur-text-image

Step: 3

blur-text-image

Ace Your Homework with AI

Get the answers you need in no time with our AI-driven, step-by-step assistance

Get Started

Recommended Textbook for

Chemistry

Authors: Jill Robinson, John McMurry, Robert Fay

8th Edition

134856236, 978-0134856230

More Books

Students also viewed these Chemistry questions

Question

Distinguish between a tangible and an intangible asset.

Answered: 1 week ago