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Heterogeneous nucleation on substrate Consider cap - shaped nucleus on the substrate. Neglect the behavior of atoms in the gas phase and on the surface.

Heterogeneous nucleation on substrate
Consider cap-shaped nucleus on the substrate.
Neglect the behavior of atoms in the gas phase and on the surface.
Figure 5-3. Schematic of basic atomistic processes on substrate surface during vapor
deposition.
G=a3r3GV+a1r2vf+a2r2fs-a2r2sv
How can I derive a1,a2,a3?
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