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Hexane can equilibrate to methyl-substituted pentanes and methylcylopentane according to: ki hexane = methylcylopentane + H2 k-1 k2 hexane = 2 methylpentane k-2 Component kcal
Hexane can equilibrate to methyl-substituted pentanes and methylcylopentane according to: ki hexane = methylcylopentane + H2 k-1 k2 hexane = 2 methylpentane k-2 Component kcal AH OOK ( mol -46.10 Ag kcal 600K mol 43.02 -31.69 45.76 n-hexane methylcylopentane 2-methylpentane hydrogen -47.63 42.39 0 0 600K in which AH ook and AG ook are the heats of formation and the Gibbs free energy of formation of the compounds at 600K from the elements, respectively [17]. Find the temperature where equal amounts of methylcylopentane and 2- methylpentane form if pure hexane is allowed to equilibrate at 1.0 atm total pressure. Also find the composition of the mixture at this temperature. At this condition the hydrocarbons are gases
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