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How can UV spectroscopy distinguish between the following pairs of compounds: ( a ) and ( b ) and Hint: identify the chromophore in each

How can UV spectroscopy distinguish between the following pairs of compounds:
(a)
and
(b)
and
Hint: identify the chromophore in each molecule and then ascertain the
position and intensity of the expected UV absorption
Explain the following data:
,max=274nm
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