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In class we derived the equation for the effectiveness factor for a porous spherical catalyst pellet and a porous slab. The Levenspiel text derived the

In class we derived the equation for the effectiveness factor for a porous spherical catalyst
pellet and a porous slab. The Levenspiel text derived the expression for diffusion and reaction
in a single cylindrical pore where the gas enters from one end of the pore. In this problem I
want you to derive the expression for the effectiveness factor for a porous cylindrical catalyst
pellet where diffusion occurs in the radial direction. Assume that the cylinder ends are
impermeable and that the length of the cylinder is much longer than the radius so end effects
can be ignored. You should assume a first order reaction (AB) with kinetics r=keffCA
(a) Start by using a differential mass balance to derive the differential equation that
describes the system. You should also state the boundary conditions for the system
(hint one of them is that the CA is finite at the center of the cylinder). You may assume
that there are no external diffusion limitations.
(b) Solve the differential equation to obtain CA as a function r.
Some information that may be helpful:
The differential equation, x2(d2ydx2)+x(dydx)-ax2y=0 has the solutions y=I0(ax)
and y=K0(ax) which are the modified Bessel functions (these functions look somewhat
like sin(x) and cos(x) multiplied by an exponential decay function) and that K0(x) goes
to negative infinity at x=0.
(c) Using your result form part (b) derive an equation for the effectiveness factor for this
system.
Useful formula:
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