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In other answers in Chegg they said the arrow going right side(->) is favored. Why is that? pKa is 16 and 5 respectively, shouldn't going

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In other answers in Chegg they said the arrow going right side(->) is favored. Why is that?

pKa is 16 and 5 respectively, shouldn't going left side arrow( (iii) conjugate base conjugate acid

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