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It is desired to determine the rate of diffusion of unreacted monomer out of a newly synthesized sheet of polymer. The sheet is thin in
It is desired to determine the rate of diffusion of unreacted monomer out of a newly synthesized sheet of
polymer. The sheet is thin in the direction compared to its lengths in the and directions, so we
assume the monomer concentration is The model to be employed assumes that the monomer.
is initially at uniform concentration and that at the sheet is immersed in a wellstirred
container of solvent in which the concentration is always negligible, with Biot number large enough to
located at we'll model only half the sheet between Mirror symmetry yields the solution in
the portion. We've assumed a nondimensionalization based on the sheet halfthickness L the
initial monomer concentration and the diffusion time
b Calculate the average monomer concentration remaining in the sheet, Based on the convergence
behavior of the FFT series in part b describe qualitatively whether or not you expect the FFT series for
to be reliable?
c Determine the outward flux of monomer at the surface, both in dimensionless and in dimensional form.
Based on the convergence behavior of the FFT series in part b describe qualitatively whether or not you
expect the FFT series for the surface flux to be reliable?
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