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(LIAIHA) LiAID BuySnH AIBN KF. 18-crown-6 L = Br, OTS, OX M = Li, MgBr. Na M= acetone LICI, DMF BnBuzNCI L = OTS NaCN

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(LIAIHA) LiAID BuySnH AIBN KF. 18-crown-6 L = Br, OTS, OX M = Li, MgBr. Na M= acetone LICI, DMF BnBuzNCI L = OTS NaCN DMO, A18-crown-6 DMSO LiBr, acetone NaBr = OTs KCN PR': (NR"3) L1 tone Ki KI L = CI 1 = 7 Nal, acetone L = Br RS H2O1. Aco | KOZ 2. KOH DMSO P(OEt)3, A L = CI, Br, 1 R'ONa AroNa DMSO THE L = CI, Br, 1 OSOR', OTF, OMs, OTS, OBs. ONS ACOH | R.NOAC L = OBS, OTS 1. 2AgCN 1. TMSCN (NH2)2CS AcSK or 2. OH7H30* NASH 1. 11 2. KCN 2, TBAP AgNO2 NaNO2 DMF TsNH 2, KOH DMF A 1. K Phthalimide 2. NHANH, HO NaN NaN DMSO, A 18-crown-6 NaSOR R'SNa ArsNa DMSO, A KSCN (LIAIHA) LiAID BuySnH AIBN KF. 18-crown-6 L = Br, OTS, OX M = Li, MgBr. Na M= acetone LICI, DMF BnBuzNCI L = OTS NaCN DMO, A18-crown-6 DMSO LiBr, acetone NaBr = OTs KCN PR': (NR"3) L1 tone Ki KI L = CI 1 = 7 Nal, acetone L = Br RS H2O1. Aco | KOZ 2. KOH DMSO P(OEt)3, A L = CI, Br, 1 R'ONa AroNa DMSO THE L = CI, Br, 1 OSOR', OTF, OMs, OTS, OBs. ONS ACOH | R.NOAC L = OBS, OTS 1. 2AgCN 1. TMSCN (NH2)2CS AcSK or 2. OH7H30* NASH 1. 11 2. KCN 2, TBAP AgNO2 NaNO2 DMF TsNH 2, KOH DMF A 1. K Phthalimide 2. NHANH, HO NaN NaN DMSO, A 18-crown-6 NaSOR R'SNa ArsNa DMSO, A KSCN

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